Villains who are under the Chaotic Evil alignment. Chaotic Evil characters often exist purely to destroy, lie whenever convenient, plunder whatever they desire, murder for pleasure, disobey the law whenever convenient and however they please, and commit evil deeds and ruin the lives of others almost always if not only for fun, all while hating on law, discipline and honor left and right and inside out combined with viewing law, discipline and honor as nothing more than a weakness.

There are in rare cases of them becoming Totalitarians or Tyrants but exceptions do exist; Major (Hellsing), Aku, Albert Wesker, Skynet, Yuuki Terumi, Gabriel Miller, Morgoth, Shao Kahn, Ramsay Bolton, and Kefka Palazzo.

Examples of Pure Evil villains that correspond to Chaotic Evil: Bill Cipher, every version of Carnage, most (if not all) versions of the Joker, Muscular, Dag, William Afton, Evolt, Gyokko, Dark Lugiel, Ridley, The Batman Who Laughs, Mephiles the Dark, Anarky, Freddy Krueger, Isaac Ray Peram Westcott, Novisor, Bullseye, Cursa, Chucky, Junko Enoshima, Sundowner, Infinity Ultron, The Lich, Gigan, and Octomus the Master.

The opposite Pure Evil is Lawful Evil, the opposite of Chaotic Good, and their complete opposite is Lawful Good.